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A one-pot synthesis of chiral nucleoside analogues, in which the aglycones are derived from natural products, is described. The amino alcohol function is protected, while the glycosylamine moiety is protected by acid-labile N-Boc groups. Two different approaches, based on the use of 2,2-dimethyl-1,3-propanediyl (DMP) acetal or alpha-hydroxy-gamma-butyrolactone (HBL) lactone and H-phosphonates (H-PO2-), were developed to assemble the key intermediate 1. The phosphoramidite formation is performed using N-trimethylsilyl-O-methyl (TMS-OMe) or 5-methylisoxazole-4-sulfonyl (MeIS) protecting groups at O-6 or N-9, respectively, to give the 9-TMS-7 and N-9-MeIS derivatives. The chiral phosphoramidites are derived from D- and L-serine. Deprotection of the aglycones gives the corresponding nucleoside analogues.Spike in government spending on ‘service’ contracts may be seen as a workaround to avoid paying President’s salary, the President said

President Muhammadu Buhari has advised Nigerians not to give a pass to state-owned enterprises (SOEs) over the recent explosion in the number of their contracts as it could be a fallout from the government’s attempt to avoid the payment of the President’s salary.

While addressing the National Conference on Diaspora Relations at the Festac Theatre in the city, the President warned that the naira and the dollar could go to “jumping up” levels as government spends close to N20bn daily on contracts with SOEs.

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